Insights into Reaction Kinetics formulating RTV-2
14 August 2025

RTV-2 silicone rubbers are two-component systems that cure at room temperature via an addition reaction (hydrosilylation) between vinyl groups in the BRB Vinyl Dimethicones (serving as the base polymer) and Si-H groups of the BRB Crosslinker series, typically in the presence of a platinum catalyst. BRB Vinyl Dimethicones are the perfect building blocks for these systems and largely determine the processing behavior, curing kinetics, and physical-mechanical performance.

The role of bimodal distribution in an RTV-2 has become increasingly recognized as a key factor in optimizing viscosity, tensile strength, and dimensional stability. This article provides a technical analysis of that role.

Bimodality refers to the presence of two dominant molecular weight fractions of BRB Vinyl Dimethicones, a low-molecular-weight (LMW) fraction and a high-molecular-weight (HMW) fraction.

This distribution is achieved by blending short-chain and long-chain BRB Vinyl Dimethicones in controlled ratios. The LMW components enhance flow and reduce initial viscosity, while the HMW polymers contribute to strength and elasticity in the cured material.

Contribution of MW to material properties of an RTV-2 system

Property

LMW component

HMW component

Pre-cure viscosity

Flow/detail reproduction


Creep resistance


Tensile & tear strength

Elastic recovery

Dimensional stability

The synergy between low- and high-molecular-weight fractions enables a well-balanced silicone material, suitable for high-detail reproduction while maintaining robust mechanical integrity.

BRB Vinyl Dimethicones serve as a functional cornerstone in RTV-2 silicone rubber systems, influencing both curing behavior and material performance. Through bimodal molecular weight distribution, manufacturers can fine-tune the balance between processability and mechanical robustness. The synergy of LMW and HMW BRB Vinyl Dimethicones provides a versatile platform that meets the high demands of modern medical and industrial applications.

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